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Part V: Sodium Sulfide Firefighting Measures
5.1 Sodium Sulfide Hazardous Characteristics: The anhydrous form is spontaneously combustible, and its dust can ignite spontaneously in air. It decomposes upon contact with acids, releasing highly toxic and flammable gases. Dust can form explosive mixtures with air. Its aqueous solution is corrosive and highly irritating. It begins to evaporate at 100°C, and the vapor can corrode glass.
5.2 Hazardous Combustion Products: Hydrogen sulfide, sulfur oxides.
5.3 Sodium Sulfide Firefighting Methods: Use water, water mist, or sand to extinguish.